I know it's probably too late for this answer to be useful for OP, but I just had to walk my uncle through getting rid of this over facetime and it was a doozie. So the app takes over the window completely and won't let anything sit in front of it. So it allows you to open task manager, but task manager opens in a window behind the "PC Store". However, it does allow keyboard controls to go to task manager. So, using the search in windows, or via Ctr+Alt+Delet open task manager. You will see it has opened in the taskbar. Click on the task manager app icon in the taskbar as if to bring it up to the front (this won't work because of the "pc store", but it makes sure your keystrokes go to task manager and not another window). Once you've got it open, hover over the task manager app icon in the taskbar, then move your mouse up slightly to hover over its window preview. This will look like you've managed to bring it to the front, but if you stop hovering, it will go away. SO, while hovering over the window preview, use the arrow keys to scroll through the list of running apps, and when you find and highlight the "pc store" task, click delete. This should end the process and it should let you have some control back. Now, you can go to settings, search for "remove apps or programs" and find the "pc app store" and uninstall it. This seems to have worked for my uncle so far. You should definitely do a malware scan like is mentioned in the other answers to double check. This method should also work for any other addware similar to this that takes over the window.
Hope this helps someone!